ARTICLE
TITLE

ONE-STEP CONVERSION OF EUGENOL TO METHYL ISOEUGENOL USING MICROWAVE IRRADIATION IN SOLVENT-FREE CONDITIONS

SUMMARY

A research on conversion of eugenol to methyl isoeugenol via one-step reaction with microwave irradiation has been carried out. Mixtures containing eugenol, sodium or potassium carbonate as solid support, with or without sodium or potassium hydroxide as base, with or without tetrabutylammonium bromide as phase transfer catalyst, with dimethyl sulfate as the methylating agent were irradiated in a domestic microwave oven for 20 - 50 seconds. It was revealed that one-step methylation and isomerization required combinations of sodium or potassium hydroxide base and tetrabutylammonium bromide. Without combination of base and TBAB only one product, i.e. methyl eugenol, was formed.

 Articles related

Bin Li,Chao Liu,Guang Yu,Yuedong Zhang,Xindong Mu    

Pretreatment or fractionation is one of the key steps for the conversion of lignocelluloses to sustainable biofuels, biomaterials or biochemicals, because pretreatment/fractionation can break the natural recalcitrance of lignocelluloses, improving the co... see more


Ayad Kareem Khan    

In the present research, a series of some azo compounds (5-9) and 1,2,3-triazoles derived from 2-methyl quinazolin-4(3H)-one were synthesized successfully by stepwise routes includes the following: 3-amino-2-methylquinazolin-4(3H)-one (3) prepared firstl... see more


Gavrilo Šekularac,Sanja Erakovic,Dušan Mijin,Vesna Pavelkic,Jasmina Stevanovic,Vladimir Panic    

For the preparation of RuO2 coatings on Ti substrate, the RuO2 was synthesized in acidic aqueous medium by simple one-step low temperature-co­ntrolled microwave (MW) irradiation. The physical composition of synthesized solid phase was analysed through pa... see more


Mehdi Omri, Frédéric Sauvage, Séma Golonu, Anne Wadouachi and Gwladys Pourceau    

In the growing context of sustainable chemistry, one of the challenges of organic chemists is to develop efficient and environmentally friendly methods for the synthesis of high-added-value products. Heterogeneous photocatalytic transformations have brou... see more

Revista: Catalysts