ARTICLE
TITLE

Catalytic Purification of Sulfur from Bituminous Impurity

SUMMARY

The aim of this study is to build a pilot plant system working in a continuous mode to purify sulfur from bituminous impurities. This study focused on the role of the added mineral salt of view to help choose and design the right and suitable purification reactor that is capable of overcoming any future problems and getting pure sulfur. The presence of these impurities deteriorates the specification of the produced sulfur and has to be removed from it. Two different processes were used in the mine both based on the carbonization of the bitumen (in two different ways) and then the separation of the carbonized material by filtration. Both processes suffered serious technical, ecological and economic problems. Search for another purification method that can overcome these problems continued, finally, it was possible to purify sulfur from accompanied bituminous impurities by treating raw sulfur at about (125-130 ºC) with certain metal salt for 10 minutes, then subjecting the mixture to a filtration step. No hydrogen sulfide gas was detected. The reaction conditions are quite mild compared with the conditions currently used in the Mishraq sulfur mine (440-500 ºC for ~ 2 hours), with a large percentage of sulfur being converted to sulfurous gases. Rather than carbonizing the bitumen, it is presumed that purification is accomplished through the formation of a complex between the hydrocarbon and the metal salt that can be deposited on the surface of the filter element. It is possible to recover the spent metal salt and reuse it again. 

 Articles related

Lenchi Nesrine,Kebbouche Salima,Khelfaoui Mohamed Lamine,Laddada Belaid,bKhemili Souad,Gana Mohamed Lamine,Akmoussi Sihem,Ferioune Imène    

Environments containing significant concentration of NaCl such as salt lakes harbor extremophiles microorganisms which have a great biotechnology interest. To explore the diversity of Bacteria in Chott Tinsilt (Algeria), an isolation program wa... see more


Ana Marija J. Balaž,Marija B. Blažic,Nikolina Popovic,Olivera L. Prodanovic,Raluca V. Ostafe,Rainer Fischer,Radivoje M. Prodanovic    

Production of soluble cellobiose dehydrogenase (CDH) mutant pro­teins previously evolved on the surface of S. cerevisiae yeast cells was estab­lished for use in biosensors and biofuel cells. For this purpose, mutant cdh genes tm (D20N, A64T, V592M), H5 (... see more


Abha Maskey,Sharon Molnar,Gerald Hankins    

Modern medicine has been focusing on proving new and alternative chemotherapeutic compounds with high tumor cytotoxicity and reduced side effects to combat drug resistance and improve drug efficacy in cancer treatment. Organometallic compounds have uniqu... see more


S. Aimukhanov, A. Suleimenov, A. Yelubay, A. Nurgaliev    

Activities comparisons of the catalyst from cerium oxide on carriers from mineral raw materials of the Pavlodar area held. Law of catalytic oxidation CO ? CxHy is investigated, The expediency estimation of Expediency of application of the catalyst on the... see more


Roberto Fiorenza, Luca Spitaleri, Antonino Gulino and Salvatore Scirè    

The catalytic performances of Ru/ceria-based catalysts in the CO preferential oxidation (CO-PROX) reaction are discussed here. Specifically, the effect of the addition of different oxides to Ru/CeO2 has been assessed. The Ru/CeO2-MnOx system showed the b... see more

Revista: Catalysts