SUMMARY
This paper is based on experimental data and provides better understanding of the mechanism of calcareous deposit formation on cathodically polarized steel surfaces exposed to synthetic seawater at 30 °C and 60 °C. The study comprises measurement of the interfacial pH of thermally sprayed aluminum (TSA) coated steel samples with and without a holiday (exposing 20% of the surface area). Tests were conducted at the corrosion potential for up to 350 h. It was experimentally determined that the local pH adjacent to the steel surface in the holiday region reached a maximum of 10.19 and 9.54 at 30 °C and 60 °C, respectively, before stabilizing at about 8.8 and 7.9 at the two temperatures. The interfacial pH on the TSA coating at 30 °C was initially 7.74 dropping to 4.76 in 220 h, while at 60 °C it increased from pH 6.41 to the range pH 7.0–8.5. The interfacial pH governed the deposition of brucite and aragonite from seawater on the steel surface cathodically polarized by the TSA. This mechanism is likely to affect the performance of TSA-coated offshore steel structures, especially when damaged in service.