Quantitative determination of potassium hydrogenperoxomonosulfate in “Ecocid S” disinfectant by cathodic voltammetry
DOI:
https://doi.org/10.24959/nphj.14.1956Keywords:
potassium hydrogenperoxomonosulfate, voltammetry, carbositall electrode, SDBS, disinfectantAbstract
The electrochemical behaviour of potassium hydrogenperoxomonosulfate (KHSO5) in the presence of sodium dodecylbenzenesulfonate (SDBS) has been studied using cathodic voltammetry at the carbositall electrode as indicating in the potential range of +1.0…–1.2 V (the reference electrode Ag, AgCl/KСl(sat)) (Ep = +0.3 V). It has been experimentally proven that the height of KHSO5 reduction peak decreases and the potential of the reduction peak is shifted toward more electronegative values with increasing of the background electrolyte pH from 0.80 to 7.17. The maximum peak (Ip) occurs at a pH of approximately 0.8 and at a pH around 5 the analytical signal almost disappears. The effect of pH on the peak potential (Ep) shows the following: when the pH value increases in the interval from 0.8 to 2, Ep remains almost constant, but Ep decreases sharply to the negative value with pH increasing over 2. It has been experimentally proven that SDBS leads to increase of the current peak and the peak potential shifts to the more electropositive side (+0.25→ +0.3V). The influence of the present SDBS has been examined. The current peak increases with the concentration of the surfactant up to 1.2×10–3 mol L–1 and then stays almost constant with the increase in the concentration of SDBS above 3.0×10–3 mol L–1. The linear relationship was observed in the KHSO5 concentration range of (1.8–9.0)×10–5 mol L–1, the calibration curve equation was Iр = (4.3±1.1)×104 с (r = 0.998). When determining KHSO5 in the test solution of “Ecocid S” disinfectant with the concentrations of 4.65×10–5, 6.20×10–5 and 7.75×10–5 mol L–1) the RSDs were 0.025, 0.023 and 0.021, respectively (δ = –0.64 ... +0.16%); LOD = 6.50×10–6 mol L–1, LOQ = 2.17×10–5 mol L–1.
References
Bakun V.А., Fedulov D.М., Osipova Е.А. et al. // Vestnik МIТKhТ. – 2009. – Vol. 4, №3. – P. 80-84.
Bengtong Ph., Thomrongsuwannakij T., Chansiripornchai N. // Thai J. Vet. Med. – 2013. – Vol. 43 (3). – P. 405-409.
Blazheyevskiy M.Ye., Mozgova O.O. // J. Chem. Pharm. Res. – 2013. – Vol. 5(11). – P. 489-496.
Hernandez A., Martro E., Matas L. et al. // J. Hosp. Infect. – 2000. – Vol. 46. – P. 203-209.
Kreyngold S.U. // Dez. delo. – 2003. – Vol. 1. – P. 45-46.
Manjunatha J.G., Kumara Swamy B.E., Mamatha G.P. et al. // Int. J. Electrochem. Sci. – 2010. – Vol. 5. – P. 1236-1245.
Marchetti V., Mancianti F., Cardini G. et al. // Vet. Res. Com. – 2006. – Vol. 30. – P. 255-261.
McCormick L., Maheshwari G. // Antiviral Res. – 2004. – Vol. 64. – P. 27-33.
Moslehifard E., Nasirpouri F., Gasemzadeh S. // J. Islamic Dent. Assoc. Iran (JIDA). – 2013. – Vol. 25 (2). – P. 127-133.
Ozkan S.A., Uslu B., Enein H.Y. // Crit. Rev. Anal. Chem. – 2003. – Vol. 33. – P. 155-181.
Ossadnik S., Schwedt G. // Fresenius J. Anal. Chem. – 2001. – Vol. 371. – P. 420-424.
Roy P.R., Okajima T., Ohsaka T. // Bioelectrochem. – 2003. – Vol. 59. – P. 11.
Ruttinger H.-H., Radschuweit A. // J. Chrom. – 2000. – Vol. 868. – P. 127-134.
Suinjevic D., Blagojevic S., Vucelic D. et al. // Electroanalysis. – 1991. – Vol. 9 (1). – P. 861-864.
Tsvirova I.М., Panteleeva L.G., Fedorova L.S. et al. Instruktsiya 1 po primeneniju sredstva ECOCID®, КRKА, Novo mesto (Slovenia) dlja tseley dezinfektsii i predsterilizatsionnoy ochistki. – M.: FGUN NII dezinfektologii Rospotrebnadzora Rossii, 2007. – 13 p.
Uslu B., Ozkan S.A. // Anal. Lett. – 2003. – Vol. 40. – P. 817-853.
Uslu B., Ozkan S.A. // Comb. Chem. High Through Screen. – 2007. – Vol. 10. – P. 495-513.
Wang H., Zhang Y., Gao Sh. et al. // CIESC J. – 2010. – Vol. 61. – P. 82-85.
Wang J. Electroanalytical Chemistry. 3rd ed., Wiley-VCH Pub., NewJerrey, 2006.
Westbroek Ph., Hakuzimana J., Gasana E. et al. // Sensors and Actuators. – 2007. – Vol. 124. – P. 317-322.
Zhang J., Oloman C.W. // J. Appl. Electrochem. – 2005. – Vol. 35. – P. 945-953.
Ziyatdinova G.K., Ziganshina E.R., Budnikov H.C. // J. Anal. Chem. – 2012. – Vol. 67 (11). – P. 869-879.
Downloads
Published
Issue
Section
License
Copyright (c) 2014 National University of Pharmacy
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).