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275.875  Articles
1 of 27.589 pages  |  10  records  |  more records»
[2+3] Dipolar cycloadditions of aromatic nitrile oxides to abietic acid esters were investigated. The reactions showed complete site selectivity and regioselectivity, while the stereoselectivity depended on the structures of the dipolarophiles.

[3+2] Cycloaddition reactions of 2-(trifluoroacetyl)vinyl ethyl ether (1) to substituted and unsubstitued 2-arylidene-5-oxopyrazolidin-2-ium-1-ides (2a–e) were studied using density functional theory (DFT) methods at the cc-pVDZ level. The mechanistic det... see more

Aim. To extend the synthetic limits of the reaction of the electrophilic intramolecular cyclization (EIC) on the examples of 5,5-disubstituted and 5-yliden substituted 3-allyl-2-thiohydantoins and the directed structural modification of 2-halogenomethyl-2... see more

In this work, the synthesis of novel triazole derivatives with barbi­turic motifs in good yields is described. The alkyne was prepared through the Knoevenagel reaction of barbituric derivatives with ortho and para O-propar­gylated hydroxybenzaldehyde. The... see more

Les approches relatives à la synthèse organique, fondées sur des réactions de cycloaddition ont pris ces dernières années une importance considérable. En effet la synthèse des composés hétérocycliques à cinq chainons tels que les isoxazolidines fait souve... see more

Các 1-Aryl-1-(2-thienyl)eten ph?n ?ng v?i 2,4-pentandion ho?c etylacetoacetat trong acid acetic sôi du?i s? có m?t c?a mangan triacetat dihydrat d? cho các 4,5-dihydrofuran m?i có ch?a vòng 2-thienyl ? v? trí 5. M?t khác, các eten này cung ph?n ?ng t... see more

Novel 1,3-oxazepine derivatives have been synthesis via (2+5) cycloaddition reaction of imines and selected cyclic carboxylic acid anhydrides by refluxing in dry benzene. Imines have been prepared by thermal condensation of 4-methyl aniline and para subst... see more

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